RESTRICTED ATSC MANUAL No. 25-3 INDUSTRIAL HYGIENE MANUAL SUPPLEMENT I Pictures of Processes Processes Toxic Agents Suggested Control Measures Health Hazards NOTICE: This document contains information affecting the national defense of the United States within the meaning of the Espionage Act, 50 U. S. C., 31 and 32, as amended. Its transmission or the revelation of its contents in any manner to an unauthorized person is prohibited by law. HEADQUARTERS, AIR TECHNICAL SERVICE COMMAND / /* Wright Field, Dayton, Ohio 15 April 1945 J.SS.CO. CIN. 4-5-45 2M RESTRICTED ATSC MANUAL No. 25-3 TSMED 25-3 Page 1 HEADQUARTERS AIR TECHNICAL SERVICE COMMAND WRIGHT FIELD JANUARY 1945 ATSC REGULATION ) NO. 25-3 ) MEDICAL Industrial Hygiene Manual, Supplement No. 1 1. Purpose: The purpose of this Regulation is to establish the Industrial Hygiene Manual, Supplement No. 1, No. 25-3 as an official guide and training aid. 2. Scope: This Manual will apply to Medical Corps officers, Sanitary Corps officers, and-enlisted men engaged in the control of occupational diseases, and will be used as a training aid for all Indus- trial Hygiene activities and tactical units within the ATSC. 3. Contents: The contents of the Manual, Supple- ment No. 1, describe toxic agents, suggested control measures and health hazards, and includes pictures of processes* 4. Supply: The office of the Surgeon, Hq. ATSC will make distribution of the Manual and be respon- sible for distribution of revisions as necessary. Command of Lieutenant General KNUDSEN: T. A. SIMS Colonel, Air Corps Chief of Administration OFFICIALS RALPH NEMO Colonel, Adjutant General's Department Adjutant General DISTRIBUTION: "A" RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Table of Contents TABLE OF CONTENTS Section Page I. Aero Repair X II. Assembled Engine Cleaning 2 III. Battery 4 IV. Blacksmith 4 V. Block Test 5 VI. Carburetor and Ignition 7 VII. Electroplating 8 VIII. Engine Cleaning 10 IX. Engine Disassembly 13 X. Foundry 15 XI. Heat Treating 10 XII. Hydraulic 17 XIII. Instrument Repair 18 XIV. Luminous Dial Repair 20 XV. Machine Shop 22 XVI. Minor Repair 23 XVII. Motor Vehicle and Miscellaneous Repair 24 XVIII. Office Appliances 26 XIX. Paint and Dope 27 XX. Plexiglas 29 XXI. Propeller 30 XXII. Radiator and Tank 31 XXIII. Rubber Tank Repair 33 XXIV. Sandblasting 33 XXV. Spark Plug Cleaning 36 XXVI. Spray Painting 37 XXVII. Trichloroethylene Degreasing 39 XXVIII. Welding 40 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Foreword Section I FOREWORD This supplement was compiled from information obtained from air depots and does not represent every operation in detail. It is intended to point out operations which offer potential health hazards and hazards known to exist under ordinary con- ditions. Ways and means of control of these conditions are suggested. Health haz- ards are enumerated for each process. SECTION I AERO REPAIR PROCESS.—Airplanes are completely overhauled and repaired including disassembly, cleaning, repair, reassembly, and complete change in type of aircraft. TOXIC AGENTS 1. Carbon tetrachloride. 2. Solvent dry cleaning (petroleum distillate). 3. Gasoline. 4. Small quantities other toxic agents such as benzol, phosgene, toluene, acetone, amyl acetate, lead, ethyl alcohol, butyl alcohol, ethyl acetate, butyl acetate, petroleum naphtha, turpentine, carbon monoxide, caustic cleaners, oils, greases. SUGGESTED CONTROL MEASURES 1. General exhaust or good natural ventilation. 2. Local exhaust ventilation for cleaning inside of planes. 3. Protective hand creams. 4. Strict personal hygiene. 3. Good housekeeping. 6. Covered solvent containers. 7. Isolation of any dope and paint operations. HEALTH HAZARDS Dermatitis may result from carbon tetrachloride, petroleum distillate (gasoline, pe- troleum naphtha), benzol, toluene, acetone, amyl acetate, lead, ethyl alcohol, butyl alcohol, ethyl acetate, butyl acetate, turpentine, caustic cleaner, oils, and greases. 1. PHOSGENE.—Very poisonous gas which affects primarily the respiratory system, causing a pulmonary edema. 2. CARBON TETRACHLORIDE.—If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning which injures permanently the kidneys and liver. 3. SOLVENT DRY CLEANING (petroleum distillate).—Gasoline, petroleum naph- tha, may produce an acute anesthetic action or may produce a chronic type of poison- ing usually associated with nervous symptoms. 4. BENZENE (benzol).—Is a very toxic material and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 5. ACETONE.—There are no cases of poisoning reported in man. Experimentally on animals, it has an acute narcotic effect. 6. ACETATE (amyl, butyl, and ethyl). —Slight possibility of causing irritation of eyes and respiratory passages and mildly anesthetic. There are no fatal poisoning cases reported in man. 7. ALCOHOL (butyl and ethyl). — May produce blood changes with renal and hepatic degeneration if inhaled over a long period of time. RESTRICTED 1 Sections l-ll RESTRICTED ATSC MANUAL No. 25-3 8. TURPENTINE.—Inhalation of heavy fumes causes symptoms of a mild anesthetic poison. It is excreted by the kidneys and nephritis is not an uncommon result of long exposure to turpentine fumes. 9. CAUSTIC CLEANER.—May produce dermatitis and conjunctivitis along with caustic effect. 10. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. 11. CARBON MONOXIDE.—If in sufficient concentration will produce anoxemia causing unconsciousness and death. SECTION II ASSEMBLED ENGINE CLEANING PROCESS.—Assembled engines are cleaned and sprayed with rust-protective material. TOXIC AGENTS 1. Rust-preventive (probably veg- etable oil butyl alcohol, 3 per- cent tertiary phenolic amine). 2. Solvent dry cleaning (petro- leum distillate). 3. Kerosene. SUGGESTED CONTROL MEASURES 1. Exhaust ventilation (booth). 2. Protective creams and ointments. 3. Protective clothing such as gloves, aprons, and boots. 4. Strict personal hygiene. 7. Booth Enclosure. 2. Spray cleaning. 3. Improper ventilation. 2 RESTRICTED RESTRICTED ATSG MANUAL No. 25-3 Section II Booth enclosure provided with an air curtain at each end to prevent escape of vapors to room. HEALTH HAZARDS Dermatitis may result from rust-preventive (probably phenolic amine), petroleum distillate, and kerosene. 1. BUTYL ALCOHOL.—May produce an acute inebriation but no fatal cases of in- dustrial poisoning published. 2. SOLVENT DRY CLEANING.—May produce an acute anesthetic action or pro- duce a chronic type of poisoning usually associated with nervous symptoms. Petro- leum distillate may also contain benzene. 3. KEROSENE. — Is a petroleum distillate. RESTRICTED 3 Sections lll-IV RESTRICTED ATSC MANUAL No. 25-3 SECTION III BATTERY PROCESS.—Batteries receive minor repairs and are recharged. TOXIC AGENTS 1. Lead. 2. Sulphuric acid. 3. Sulphur dioxide. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (hood type). 2. Rubber gloves, aprons, and face shields for operators. 3. Isolation of process. HEALTH HAZARDS Dermatitis may be caused by lead and sulphuric acid. 1. LEAD.—May produce any of the symptoms and signs of plumbism. 2. SULPHURIC ACID.—Chief danger is in spillage or breakage of containers. 3. SULPHUR DIOXIDE. — Produces an acute irritation of upper respiratory tract. Prolonged exposure to small amount may cause dyspnea, fatigue, and sluggishness. SECTION IV BLACKSMITH PROCESS.—Tools and parts are heated in a forge and formed TOXIC AGENTS 1. Carbon monoxide. 2. Sulphur gases. 3. Excessive heat. SUGGESTED CONTROL MEASURES 1. Local exhaust or good natural ventilation for forge. 2. Isolation of process. 3. General exhaust ventilation. 4. Good housekeeping. HEALTH HAZARDS Dermatitis may be caused by sulphur gases. 1. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia causing loss of consciousness and death. 2. SULPHUR GASES.—Most important is sulphur dioxide, which produces an acute irritation of upper respiratory tract. Prolonged exposure to small amount may cause dyspnea, fatigue, and sluggishness. 3. EXCESSIVE HEAT.—May produce heat exhaustion with loss of body fluids and chlorides. 4 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section IV 1. Exhaust ventilated hood. 2. Protective clothing. An example of good housekeeping. 1. Local exhaust ventilation. Local exhaust hood over forge. RESTRICTED Section V RESTRICTED ATSC MANUAL No. 25-3 SECTION V BLOCK TEST PROCESS.—New motors and repaired motors are given an operating test, cleaned, prepared for storage and shipping. TOXIC AGENTS 1. Carbon monoxide. 2. Solvent dry cleaning (petrole- um distillate). 3. Noise. 4. Kerosene, oils, greases. SUGGESTED CONTROL MEASURES 1. Positive pressure ventilation of control room. 2. Local exhaust ventilation on oil return system. 3. Protective hand creams. 4. Protective ear plugs. 5. Proper design and location of block test buildings. HEALTH HAZARDS Dermatitis may be caused by solvent dry cleaning, kerosene, oils, and greases. 1. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia, causing unconsciousness and death. 2. PETROLEUM DISTILLATES (solvent dry cleaning and kerosene).—May pro- duce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 3. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. Outlet for positive pressure ventilation. Operator’s window. RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section VI SECTION VI CARBURETOR AND IGNITION PROCESS.—Carburetors, magnetos, generators, and ignition parts are dismantled, cleaned, repaired, and reassembled. TOXIC AGENTS 1. Solvent dry cleaning (petro- leum distillate). 2. Carbon tetrachloride. 3. Small amounts of lead, decompo- sition products of commercial fluxes, hydrochloric acid. SUGGESTED CONTROL MEASURES 1. General ventilation (exhaust or supplied air type). 2. Covered solvent containers. 3. Protective hand creams. HEALTH HAZARDS Dermatitis may be caused by solvent dry cleaning, lead, hydrochloric acid, and fluxes. 1. SOLVENT DRY CLEANING.—May produce an acute anesthetic action or pro- duce a chronic type of poisoning usually associated with nervous symptoms. 2. LEAD.—May produce any of the characteristic signs and symptoms of plumbism. 3. HYDROCHLORIC ACID.—Usual danger is from spillage in open flame. Pos- sibility of production of phosgene, which may produce edema of lungs and death. 4. CARBON TETRACHLORIDE.—If in sufficient concentration, may cause an acute narcosis. Most common effect is chronic poisoning which injures permanently the kidneys and liver. 1. Covered solvent containers. 2. Supplied air ventilation. General exhaust ventilation at a carburetor test stand in an overseas installation. RESTRICTED 7 Section VII RESTRICTED ATSC MANUAL No. 25-3 Exhaust ventilated cleaning bench and exhaust ventilated cleaning booth. SECTION VII ELECTROPLATING PROCESS.—Parts and fittings suspended in a chemical bath are electroplated by means of electric hydrolysis. TOXIC AGENTS 1. Sodium cyanide. 2. Cadmium oxide. 3. Oxides of nitrogen. 4. Hydrofluoric acid. 5. Other chemicals which may be used are lead carbonate, copper sulphate, nickel sul- phate, nickel chloride, phos- phoric acid, acetic acid, caus- tic soda, chromic acid. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (hori- zontal slot type preferable). 2. General exhaust ventilation. 3. Isolation of process. 4. Gloves, aprons, face shields, and goggles for operators. 5. Low temperature of solution and reduced rate of operations of pro cess in absence of ventilation. 6. Protective nasal ointments. HEALTH HAZARDS Dermatitis may result from chrome, sodium cyanide, hydrofluoric acid, copper sul- phate, nickel sulphate and chloride, and caustic soda. 8 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section VII 1. SODIUM CYANIDE.—Effects due to hydrogen cyanide, which is a powerful protoplasmic poison and causes a cessation of oxidation in the blood. This may also be absorbed through the skin. 2. CADMIUM OXIDE. —Systemic effects due to edema of lungs and pneumonitis if inhaled. Associated with digestive symptoms if ingested. 3. OXIDES OF NITROGEN.—Cause an edema of the lungs and if in sufficient concentration may cause death. 4. HYDROFLUORIC ACID.—Usually produces a local caustic effect on skin and mucous membrane. There is a small possibility of chronic poisoning. 5. LEAD CARBONATE.—May cause any of symptoms or signs of plumbism. 6. COPPER SULPHATE.—Chronic copper poisoning has not been proved but is thought by some to cause hemochromatosis. Possibility of S02 causing upper respir- atory irritation can not be overlooked. 7. NICKEL SULPHATE AND CHLORIDE.-Nickel carbonyl (mixture of nickel and carbon) is the only compound of nickel that produces system poisoning. 8. PHOSPHORIC ACID.—Slight danger of formation of phosphorus. 9. ACETIC ACID.—May produce temporary irritation of gastrointestinal tract and respiratory tract. 10. CAUSTIC SODA.—May produce a dermatitis or conjunctivitis along with caus- tic effect. 11. CHROMIC ACID.—Produces dermatitis with chrome ulcers, which are very slow healing. An example of lateral slot type ventilation. Small plating tanks provided with lateral slot type ventilation. RESTRICTED Section VIII RESTRICTED ATSC MANUAL No. 25-3 SECTION VIII ENGINE CLEANING PROCESS.—Engine parts are degreased by hand cleaning methods and by dipping in tanks. TOXIC AGENTS 1. Carbon tetrachloride. 2. Turco fuzee (80 percent ethyl- ene dichloride, 20 percent cresol). 3. Mixture (50 percent carbon tetrachloride, 50 percent gaso- line). 4. Solvent dry cleaning (petro- leum distillate). 5. Caustic cleaners (soda ash, Oakite). 6. Other solvents such as gaso- line and turpentine. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (hori- zontal slot type) and good natural ventilation. 2. Strict personal hygiene. 3. Protective creams and ointments. 4. Protective clothing. 5. Use of lanolin oil hand cleanser. 6. Isolation of process. 1. Local exhaust ventilation. 2. Protective clothing. 10 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section VIII Lateral slot type exhaust ventilation. HEALTH HAZARDS Dermatitis may result from carbon tetrachloride, turco fuzee, gasoline, solvent dry cleaning, caustic cleaners, and turpentine. 1. CARBON TETRACHLORIDE.—If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning which effects primarily the liver and kidneys. 2. TURCO FUZEE (80 percent ethylene dichloride and 20 percent cresol). a. Ethylene dichloride, if in sufficient concentration, is narcotic and if continued over a long period of time will produce edema of lungs and degenerative changes in the kidney. b. Gasoline (petroleum distillate) has an acute narcotic effect and may contain up to 20 percent benzene (benzol). 3. SOLVENT DRY CLEANING (petroleum distillate).—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 4. CAUSTIC SODA.—May produce a dermatitis or conjunctivitis along with caustic effect. 5. TURPENTINE. —Inhalation of heavy fumes causes symptoms of a mild anesthetic poison. It is excreted by the kidneys and nephritis is not an uncommon result of long exposure to turpentine fumes. RESTRICTED 11 Section VIII RESTRICTED ATSC MANUAL No. 25-3 Use of enclosed and exhaust ventilated system in conveyor line cleaning method, Part of exhaust ventilated and enclosed system in conveyor line cleaning method. 12 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section IX SECTION IX ENGINE DISASSEMBLY PROCESS.—Engines are manually disassembled into component parts and partially cleaned. TOXIC AGENTS 1. Carbon tetrachloride. 2. Mixture of 50 percent carbon tetrachloride, 50 percent gaso- line. 3. Solvent dry cleaning commer- cial petroleum distillate. 4. Oils, greases. 5. Other volatile solvents. SUGGESTED CONTROL MEASURES 1. Local exhaust (lateral type) or good natural ventilation. 2. Strict personal hygiene, protec- tive clothing, protective ointments and creams, and use of lanolin oil hand cleanser. HEALTH HAZARDS Dermatitis may be caused by carbon tetrachloride, gasoline, petroleum distillates, oils, and greases. 1. CARBON TETRACHLORIDE.—In sufficient concentration, may cause an acute narcosis. Most common effect is chronic poisoning, which injures primarily the kidneys and liver. 2. PETROLEUM DISTILLATES (gasoline and solvent dry cleaning).—May pro- duce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 3. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. General view of engine disassembly. RESTRICTED 13 Section IX RESTRICTED ATSC MANUAL No. 25-3 1. Hand cleaning of parts using a covered container. 2. Lanolin oil dispenser. Exhaust ventilated spray cleaning booth. Spray cleaning in exhaust ventilated booth. 14 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section X SECTION X FOUNDRY PROCESS.—Molds are prepared, various metals melted and poured into molds, cast- ings removed from molds by "shake out,” castings ground and buffed. TOXIC AGENTS 1. Silica. 2. Carbon monoxide. 3. Metal fumes. 4. Excessive heat. SUGGESTED CONTROL MEASURES 1. General exhaust ventilation. 2. Approved type dust respirators. 3. Good housekeeping. 4. Use of nonsilica parting compound. HEALTH HAZARDS Dermatitis may be caused by fumes of certain metals that are being used in the foundry. 1. SILICA. —May produce silicosis if dust count is not controlled. 2. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia, causing unconsciousness and death. 3. METAL FUMES.—May cause different types of poisoning according to the types of metals that are used. 4. EXCESSIVE HEAT.—May produce heat exhaustion with loss of body fluids and chlorides. 7. Possible carbon monoxide from gas furnace. 2. Metal fumes. 3. “Wefted down” sand. RESTRICTED 15 Section XI RESTRICTED ATSC MANUAL No. 25-3 SECTION XI HEAT TREATING PROCESS.—Tools and parts are tempered and hardened by heat treating. TOXIC AGENTS 1. Sodium cyanide. 2. Carbon monoxide. SUGGESTED CONTROL MEASURES 1. General exhaust ventilation. 2. Individual exhaust pipe for cyanide. 3. Strict personal hygiene. HEALTH HAZARDS Dermatitis may be caused by cyanides. 1. SODIUM CYANIDE.—Effects usually due to hydrogen cyanide, which is a pow- erful protoplasmic poison and causes a cessation of oxidation in the blood. This may also be absorbed through the skin. 2. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia, causing unconsciousness and death. Individual exhaust pipe Exhaust ventilated cyanide bath. 16 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XII SECTION XII HYDRAULIC PROCESS.—Hydraulic parts of airplanes are disassembled, cleaned, repaired, some- times brush painted, and reassembled. TOXIC AGENTS 1. Carbon tetrachloride. 2. Solvent dry cleaning (petrole- um distillate). 3. Mixture 50 percent carbon tetra- chloride and 50 percent kerosene. 4. Benzene. 5. Alcohol. 6. Carbon black. SUGGESTED CONTROL MEASURES 1. General exhaust ventilation or good natural ventilation. 2. Local exhaust ventilation for con- tinuous cleaning operations. 3. Covered solvent containers. 4. Protective creams and oint- ments. 5. Strict personal hygiene. 6. Use of gloves where possible. HEALTH HAZARDS Dermatitis may result from petroleum distillate, methyl alcohol (usually due to de naturants), carbon tetrachloride, and benzol. Covered solvent container. RESTRICTED 17 Sections XII-XIII RESTRICTED ATSC MANUAL No. 25-3 1. CARBON TETRACHLORIDE.—If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning which effects primarily the liver and kideys. 2. SOLVENT DRY CLEANING (petroleum distillate).—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. Petroleum distillates may also contain benzene. 3. BENZENE (benzol).—Is a very dangerous toxin and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 4. METHYL ALCOHOL.—May produce an acute inebriation with an atrophy of optic nerve, also symptoms of chronic poisoning. 5. CARBON BLACK.—If prolonged, the dust may produce anthracosis. SECTION XIII INSTRUMENT REPAIR PROCESS.—All types of delicate instruments are disassembled, cleaned, reassembled, and calibrated. TOXIC AGENTS 1. Mixture of 50 percent carbon tet- rachloride, 50 percent gasoline. 2. Stoddard’s solvent (commercial organic solvent). 3. Solvent dry cleaning (petrole- um distillate). 4. Other toxic agents such as am- monia, alcohol, miscellaneous organic solvents SUGGESTED CONTROL MEASURES 1. Properly designed ventilated spray booth for cleaning. 2. Covered solvent containers. 3. Protective creams and oint- ments. Covered solvent container. 18 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XIII Cleaning table with lateral exhaust ventilation to remove solvent vapors. 7. Spray booth 2. Ventilation. HEALTH HAZARDS Dermatitis may be produced by carbon tetrachloride, gasoline, Stoddard’s solvent, solvent dry cleaning, and alcohol. 1. CARBON TETRACHLORIDE.—If in sufficient concentration, may cause an acute narcosis. Most common effect is chronic poisoning, which affects primarily the liver and kidneys. 2. PETROLEUM DISTILLATE (Stoddard’s solvent, solvent dry cleaning, gasoline). —May produce an acute anesthetic action or may produce a chronic type of poison- ing usually associated with nervous symptoms. Petroleum distillates may also contain benzene. 3. ALCOHOL.—May produce an acute inebriation or other changes dependent on type of alcohol used. RESTRICTED 19 Section XIV RESTRICTED ATSC MANUAL No. 25-3 SECTION XIV LUMINOUS DIAL REPAIR PROCESS.-Used luminous dials are scraped and repainted, and new dials are painted with luminous paint. SUGGESTED CONTROL MEASURES 1. Special designed workroom equipped with argon light inspection room, approved hoods, and exhaust ventilation. 2. Compulsory personal hygiene. 3. Proper storage and handling of luminous compound. 4. Good housekeeping. 5. Dry paint removal under liquid or ventilated hood and operator pro- vided with approved supplied air respirator. TOXIC AGENTS 1. Radioactive luminous paint. 2. Radon. 3. Gamma radiation. HEALTH HAZARDS Small possibility of burn from gamma radiation. RADIOACTIVE PAINT.—Greatest possibility is inhalation and ingestion of paints, causing a chronic type of poisoning which affects primarily the bones. 1. Local exhaust ventilation. 2. Hood. 3. Lead container for wiping paper. Incorrect method of scraping old dial. 20 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XIV Dial scraping prior to repainting. Note down- draft ventilated table in use at an overseas installation. Ventilated radium dial storage cabinet. Dial painting booths. Note rounded corners and well designed hoods. RESTRICTED 21 Section XV RESTRICTED ATSC MANUAL No. 25-3 SECTION XV MACHINE SHOP PROCESS. —Airplane parts and tools are machined, finished, and polished. TOXIC AGENTS 1. Cutting oils and greases. 2. Synthetic resin and asbestos dust. SUGGESTED CONTROL MEASURES 1. Strict personal hygiene. 2. Protective creams and ointments, 3. Local exhaust ventilation of dusty processes. HEALTH HAZARDS Dermatitis may be produced by cutting oils, greases, and synthetic resin ASBESTOS.—A prolonged exposure may produce asbestosis. 22 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XVI SECTION XVI MINOR REPAIR PROCESS.—Airplanes receive first and second echelon maintenance. TOXIC AGENTS 1. Carbon , tetrachloride. 2. Solvent dry cleaning (petrole- um distillate). 3. Mixture 30 percent carbon tetrachloride, 50 percent gasoline. 4. Small quantities other toxic agents such as benzol, gasoline, toluene, acetone, amyl acetate, lead, ethyl alcohol, butyl alcohol, ethyl acetate, butyl acetate, petroleum naphtha, turpentine, caustic cleaners, oils, and greases. SUGGESTED CONTROL MEASURES 1. General exhaust or good natural ventilation. 2. Local exhaust ventilation for cleaning inside of planes. 3. Protective hand cream. 4. Strict personal hygiene. 5. Good housekeeping. 6. Other measures are covered solvent containers and isola- tion of paint and dope operations. Minor repair. 23 RESTRICTED Sections XVI-XVII RESTRICTED ATSC MANUAL No. 25-3 HEALTH HAZARDS Dermatitis may be caused by carbon tetrachloride, petroleum distillate (gasoline and petroleum naphtha), benzol, toluene, acetone, amyl acetate, lead, ethyl alcohol, butyl alcohol, ethyl acetate, butyl acetate, turpentine, caustic cleaners, oils, and greases. 1. CARBON TETRACHLORIDE.—If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning which injures primarily the kidneys and liver. 2. PETROLEUM DISTILLATES (gasoline and petroleum naphtha).—May produce an acute anesthetic action or may produce a chronic type of poisoning usually asso- ciated with nervous symptoms. 3. BENZENE (benzol).—Is a very toxic material and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 4. TOLUENE. — If in sufficient concentration has a narcotic action. May produce death. Toluene is methyl benzene. 3. ACETONE.—There are no cases of poisoning reported in man. Experimentally on animals, has an acute narcotic effect. 6. ACETATE (amyl, butyl and ethyl). — Slight possibility of causing irritation of eyes and respiratory passages and mildly anesthetic. There are no fatal poisoning cases reported in man. 7. ALCOHOL (butyl).—May produce blood changes with renal and hepatic degen- eration if inhaled over a long period of time. 8. TURPENTINE. —Inhalation of heavy fumes causes symptoms of a mild anesthetic poison. It is excreted by the kidneys and nephritis is not an uncommon result of long exposure to turpentine fumes. 9. CAUSTIC CLEANER.—May produce dermatitis and conjunctivitis along with caustic effect. 10. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. SECTION XVII MOTOR VEHICLE AND MISCELLANEOUS REPAIR PROCESS.—Repair of gasoline motors and related equipment. TOXIC AGENTS 1. Carbon monoxide. 2. Gasoline. 3. Lead. 4. Asbestos. 5. Oils and greases. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation. 2. Protective clothing, gloves, aprons. 3. Approved-type air line respirators for continued exposure or approved- type toxic dust respirator for intermittent exposures to dusty operations. 4. Protective hand creams. 5. Strict personal hygiene. HEALTH HAZARDS Dermatitis may be caused by petroleum distillate (gasoline and petroleum naphtha), oils, and greases. 1. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia, causing unconsciousness and death. 24 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XVII Exhaust ventilated grinding wheel for brake shoe grinding. Exhaust ventilating system for removal of carbon monoxide during motor tune-up. i Exhaust ventilating system for removal of carbon monoxide during motor tune-up. 2. GASOLINE.—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 3. LEAD.—May produce any of the symptoms and signs of plumbism. 4. ASBESTOS.—A prolonged exposure may produce asbestosis. 5. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. RESTRICTED 25 Section XVIII RESTRICTED ATSC MANUAL No. 25-3 SECTION XVIII OFFICE APPLIANCES PROCESS.—Typewriters are cleaned, repaired, and adjusted. TOXIC AGENTS 1. Naphtha. 2. Benzene. 3. Carbon tetrachloride. 4. Kerosene. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation. 2. Isolation of process. 3. Protective clothing. 4. Protective creams and ointments. HEALTH HAZARDS Dermatitis may be caused by carbon tetrachloride, petroleum distillates (petroleum naphtha, kerosene), and benzene. 1. CARBON TETRACHLORIDE. — If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning which injures primarily the kid- neys and liver. 2. BENZENE (benzol). —Is a very toxic material and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 3. PETROLEUM DISTILLATES (petroleum naphtha, kerosene).—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. Note the absence of ventilation for solvent spraying. 26 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XIX SECTION XIX PAINT AND DOPE PROCESS. — Surfaces of airplanes such as bodies, wings, etc., are doped (spray and hand), and painted (spray and hand). Hand painting and dope. 1. Position of work. 2. Downdraft general exhaust ventilation. Spray paint and dope. 7. Booth enclosure. 2. Exhaust fans. Using a supplied air respirator in vehicle spray painting. RESTRICTED 27 Section XIX RESTRICTED ATSC MANUAL No. 25-3 Hand application of paint and dope to fabric-covered wing sections. Downdraft exhaust ventilation through floor grilles should be employed. TOXIC AGENTS 1. Benzol. 2. Toluene. 3. Acetone. 4. Amyl acetate. 5. Lead paint. 6. Othel toxic agents such as ethyl alcohol, butyl alcohol, ethyl acetate, butyl acetate, petroleum naphtha, turpentine. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (booth). 2. Approved supplied air respirator. 3. Approved chemical cartridge-type respirator for short exposures. 4. Closed solvent containers and separate storage of bulk solvents. 3. Isolation of process. HEALTH HAZARDS Dermatitis may be produced by benzol, toluene, acetone, acetates, lead paint, alcohols, turpentine, and petroleum naphtha. 1. BENZOL.—Is a very toxic material and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 2. TOLUENE.—If in sufficient concentration, has a narcotic action and may produce death. Toluene is methyl benzene. 3. ACETONE.—There are no cases of poisoning reported in man. Experimentally on animals has an acute narcotic effect. 4. ACETATES (amyl, butyl, ethyl). —Slight possibility of causing irritation of eyes and respiratory passages and is slightly anesthetic. 5. LEAD PAINTS.—May produce any of characteristic signs or symptoms of plumbism. 6. ALCOHOL (ethyl and butyl).—May produce blood changes with renal and hepatic degeneration if inhaled over a long period of time. 7. PETROLEUM NAPHTHA.—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 8. TURPENTINE.—Inhalation of heavy fumes causes symptoms of a mild anesthetic poison. It is excreted by the kidneys and nephritis is not an uncommon result of long exposure to turpentine fumes. 28 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XX SECTION XX PLEXIGLAS PROCESS.—Plexiglas is drilled, ground, cut, and shaped. TOXIC AGENTS 1. Small quantities ethylene dichloride and monomeric methyl methacrylate. SUGGESTED CONTROL MEASURES 1. General exhaust or good natural ventilation. 2. Covered solvent containers. HEALTH HAZARDS Ethylene dichloride may produce dermatitis. ETHYLENE DICHLORIDE.—May produce an acute anesthetic action and, if pro- longed, may produce death. Action similar to that of carbon tetrachloride and chloroform. 29 RESTRICTED Section XXI RESTRICTED ATSC MANUAL No. 25-3 SECTION XXI PROPELLER PROCESS.—Airplane propellers are dismantled, cleaned, adjusted, reassembled, and balanced. TOXIC AGENTS 1. Trichloroethylene. 2. Carbon tetrachloride. 3. Solvent dry cleaning (petroleum distillate). 4. Small amounts of oils and greases. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (horizontal slot type). 2. Protective hand creams. 3. Strict personal hygiene and use of gloves where possible. 4. Lower temperature of solvent and reduce rate of operation. HEALTH HAZARDS Dermatitis may be caused by trichloroethylene, solvent dry cleaning, and oils and greases. 1. TRICHLOROETHYLENE.—In sufficient concentration, is an acute narcotic poison which is almost double that of carbon tetrachloride. In the presence of a flame, the vapors may form phosgene. Long continued exposure to trichloroethylene has been held responsible for lesions to the optic and trigeminal nerves, and may exert a damaging effect on any part of the central nervous system. 2. SOLVENT DRY CLEANING.—May produce an acute anesthetic action or may produce a chronic type of poisoning, usually associated with nervous symptoms. 3. OILS AND GREASES.—Usual damage is an oil dermatitis which can be con- trolled by proper corrective measures. 4. CARBON TETRACHLORIDE.—If in sufficient concentration, may cause an acute narcosis. Most common effect is chronic poisoning which injures permanently the kidneys and liver. Cleaning operations and improper ventilation. 30 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XXII SECTION XXII RADIATOR AND TANK PROCESS.—Radiators are dismantled, cleaned, repaired, and reassembled; metal tanks are cleaned and repaired. TOXIC AGENTS 1. Lead. 2. Ultraviolet radiations. 3. Gasoline. 4. Carbon monoxide. 5. Caustic cleaning solutions (soda ash). 6. Other toxic agents such as metal fumes, hydrochloric acid, gaseous decomposition of rod coatings. SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation (hood type). 2. General exhaust ventilation. 3. Goggles (gas weld). 4. Protective hand creams. Local exhaust ventilation for solder pot. Solvent cleaning of oil coolers. Note the use of exhaust ventilation. RESTRICTED 31 Section XXII RESTRICTED ATSC MANUAL No. 25-3 Exhaust ventilation applied to lead melting and soldering. Exhaust ventilation for dipping radiators in hot metal to release cores. HEALTH HAZARDS Dermatitis may result from lead, ultraviolet radiation, gasoline, caustic cleaning solu- tions, hydrochloric acid, and fluorides. 1. LEAD.—May produce any of symptoms or signs associated with plumbism. 2. ULTRAVIOLET RADIATION.—May produce flash burn of the eyes associated with intense pain and photophobia. 3. GASOLINE.—May produce an acute anesthetic action or may produce a chronic type of poisoning usually associated with nervous symptoms. 4. CARBON MONOXIDE.—If in sufficient concentration will produce anoxemia causing unconsciousness and death. 5. CAUSTIC CLEANING SOLUTIONS.—May produce a dermatitis and conjunc- tivitis along with caustic effect. 6. METAL FUMES.—May produce metal fume fever along with chronic poisoning from metals being welded. 7. HYDROCHLORIC ACID.—Usual danger is from spillage in open flame. Possi- bility of production of phosgene, which may produce edema of the lungs and death. 8. ROD COATING.—Gaseous decomposition of welding rods used to weld monel contain fluorine, which is an irritant to upper respiratory tract and skin. 32 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XXIII SECTION XXIII RUBBER TANK REPAIR PROCESS.—Self-sealing rubber tanks are cleaned, patched, and recoated. TOXIC AGENTS 1. Benzol. 2. Ethylene dichloride. 3. Toluene. 4. Gasoline. 5. Other toxic agents such as ethyl acetate, ethyl alcohol, methyl ethyl ketone, petroleum naphtha. SUGGESTED CONTROL MEASURES 1. General exhaust ventilation. 2. Local exhaust ventilation or blow (tanks). 3. Covered solvent containers. 4. Segregation of process. 5. Other measures are strict personal hygiene, protective clothing, protective ointments and creams. HEALTH HAZARDS Dermatitis may be caused by benzol, ethylene dichloride, toluene, gasoline, ethyl acetate, ethyl alcohol, methyl ethyl ketone, and petroleum naphtha. 1. BENZENE (benzol).—Is a very toxic material and usually presents a picture of aplastic anemia. This type of clinical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. 2. TOLUENE.—If in sufficient concentration, has a narcotic effect and may produce death. Toluene is methyl benzene. 3. PETROLEUM DISTILLATES (gasoline and petroleum naphtha).—May produce an acute anesthetic action or produce a chronic type of poisoning usually associated with nervous symptoms. Exhaust ventilation of fuel cells. RESTRICTED 33 Section XXIII RESTRICTED ATSC MANUAL No. 25-3 Using a supplied air respirator in entering a fuel cell. Lateral exhaust ventilation on table used for de-icer repair. 4. ETHYL ACETATE.—Slight possibility of causing irritation of eyes and respira- tory passages. Is mildly anesthetic. 5. ETHYL ALCOHOL.—May produce an acute inebriation or, if useu over a long period of time, produce damage to liver and kidneys. 6. ETHYLENE DICHLORIDE.—May produce an acute anesthetic action and, if prolonged, may produce death. Action similar to that of carbon tetrachloride and chloroform. 7. METHYL ETHYL KETONE.—Experimentally on animals has an acute narcotic effect. There are no cases of poisoning reported in man. 34 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XXIV SECTION XXIV SANDBLASTING PROCESS.—Engine parts and castings are cleaned by sandblasting. TOXIC AGENTS 1. Silica. 2. Lead. 3. Cadmium. SUGGESTED CONTROL MEASURES 1. Commercial cabinet of proper design. 2. Substitution of steel grit for sand. 3. Approved-type dust respirator (temporary operations). 4. Approved-type supplied air respirator. 5. Rubber gloves and aprons. 6. Isolation of process. 7. Good housekeeping and maintenance of equipment. 8. Strict personal hygiene. Commercial cabinet and protective clothing. RESTRICTED 35 Sections XXIV-XXV RESTRICTED ATSC MANUAL No. 25-3 HEALTH HAZARDS Dermatitis may be caused by lead. 1. SILICA. — Persons exposed to dust, especially silica, over a long period of time may develop pneumoconiosis. 2. LEAD.—May produce any of the characteristic signs and symptoms of plumbism. 3. CADMIUM. —Systemic effects due to edema of the lungs and pneumonitis if inhaled; associated with digestive symptoms if ingested. SECTION XXV SPARK PLUG CLEANING PROCESS.—Spark plugs are disassembled, points cleaned by sandblasting, repaired, adjusted, and tested. TOXIC AGENTS 1. Silica. 2. Carbon tetrachloride. 3. Solvent dry cleaning (petroleum distillate). SUGGESTED CONTROL MEASURES 1. Local exhaust ventilation. 2. Approved air-line respirators. 3. Approved dust-type respirator. 4. Isolation of process. 5. Substitution of nontoxic materials. HEALTH HAZARDS Dermatitis may result from carbon tetrachloride and solvent dry cleaners. 1. SILICA.—May produce silicosis if dust count is not controlled. 2. CARBON TETRACHLORIDE.—If in sufficient concentration may cause an acute narcosis. Most common effect is chronic poisoning, which effects primarily the liver and the kidneys. 3. SOLVENT DRY CLEANER (petroleum distillate).—May produce an acute anesthetic action or may produce a chronic type of poisoning associated mainly with nervous symptoms. Petroleum distillate may also contain benzene. Exhaust ventilated booth for removal of solvent vapors. 36 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XXVI SECTION XXVI SPRAY PAINTING PROCESS.—Engine parts such as crankcases, exhaust pipes, and new castings are spray painted. TOXIC AGENTS 1. Lead. 2. Toluene. 3. Xylene. 4. Turpentine. 5. Mineral spirits. 6. Naphthenate. 7. Metallic paint pigments. 8. Thinners such as ethyl alcohol, butyl alcohol, amyl acetate, butyl acetate, ethyl acetate, petroleum naphtha, and sometimes benzene. SUGGESTED CONTROL MEASURES 1. Water curtain spray booth properly ventilated. 2. Approved chemical cartridge-type respirator for temporary operations. 3. Isolation of process. 4. Bulk solvents stored separately. Paint spray booths. Water curtain ventilated spray booth. RESTRICTED 37 Section XXVI RESTRICTED ATSC MANUAL No. 25-3 Water curtain ventilated spray booth. Paint spray booth. Paint spray booth. RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Sections XXVI-XXVII HEALTH HAZARDS Dermatitis may be caused by lead, toluene, xylene, turpentine, naphthenate, metallic paint pigments, alcohol, butyl acetate, ethyl acetate, petroleum naphtha, and benzene (benzol). 1. LEAD.—May produce any of the characteristic signs and symptoms of plumbism. 2. TOLUENE AND XYLENE. — In sufficient concentration, have narcotic action and may produce death. Toluene is methyl benzene and xylene is dimethyl benzene. 3. TURPENTINE.—Inhalation of heavy fumes causes symptoms of a mild anesthetic poison. It is excreted by the kidneys and nephritis is not an uncommon result of long exposure to turpentine fumes. 4. NAPHTHENATE AND NAPHTHA (petroleum distillates).-May produce an acute anesthetic action or produce a chronic type of poisoning usually associated with nervous symptoms. Petroleum distillates may also contain benzene. 5. METALLIC PAINT PIGMENTS.—May produce any type of metallic poisoning as long as metal is contained in paint. 6. BUTYL ALCOHOL.—May produce blood changes with renal and hepatic degen- eration if inhaled over a long period of time. 7. BUTYL AND ETHYL ACETATE.—May cause a slight irritation of the eyes and air passages. Strong vapors are slightly anesthetic. 8. BENZENE.—Is a very toxic material and usually presents a picture of aplastic anemia. This type of chemical picture is seen after prolonged exposure. The acute type of poisoning produces inebriation. SECTION XXVII TRICHLOROETHYLENE DEGREASING PROCESS.—Engine parts are degreased by dipping in a tank. TOXIC AGENTS 1. Trichloroethylene. SUGGESTED CONTROL MEASURES 1. Local exhaust (horizontal slot type) ventilation. 2. Proper installation and operation of commercial degreasers. 3. Use of gloves and protective creams. 4. Reduce solvent level and rate of operation. 5. Keep lid of tank closed as much as possible. 6. Approved air-line type respirator for cleaning sumps. 7. Observe all precautions as recom- mended by manufacturer of equipment. 8. Isolation of process. HEALTH HAZARDS Dermatitis may be caused by trichloroethylene. TRICHLOROETHYLENE.—In sufficient concentration is an acute narcotic poison which is almost double that of carbon tetrachloride. In the presence of a flame, the vapors may form phosgene. Long continued exposure to trichloroethylene has been held responsible for lesions to the optic and trigeminal nerves, and may exert a dam- aging effect on any part of the central nervous system. Trichloroethylene may also cause dermatitis. RESTRICTED 39 Sections XXVII-XXVIII RESTRICTED ATSC MANUAL No. 25-3 7. Follow manufacturer's instruc- tions, “Lid must be closed when not in use.” Water jacketed degreaser with hinged covers. This is mechanically exhausted and thermostatically con- trolled. Follow instructions carefully. Keep doors closed. Do not breathe toxic vapors. 2. Water jacket condenser for condensing vapors. SECTION XXVIII WELDING PROCESS.—Various metal parts are welded by means of an electric welding arc or oxyacetylene welding torch. TOXIC AGENTS 1. Ultraviolet and infrared radiations. 2. Metal fumes. 3. Gaseous decomposition of rod coating. 4. Excessive heat. 5. Fluorides (when welding monel). 6. Other toxic substances are possible, such as oxides of nitrogen, and carbon monoxide. SUGGESTED CONTROL MEASURES 1. Protective helmet, shield, gloves, and apron (electric weld). 2. Goggles (gas weld). 3. Isolation of process. 4. General or local exhaust ventilation. 5. Portable or permanent black shield to protect adjacent workers. HEALTH HAZARDS Dermatitis may be caused by ultraviolet and infrared radiation, and fluorine. 1. ULTRAVIOLET AND INFRARED RADIATIONS.-May produce flash burns of the eyes, associated with intense pain and photophobia. 2. METAL FUMES.—May produce poisoning from fumes of metals being welded, and metal fume fever. 3. EXCESSIVE HEAT.—May produce heat exhaustion with loss of body fluids and chlorides. 4. FLUORIDES.—May produce fluorine which is an irritant to upper respiratory tract and skin. 5. OXIDES OF NITROGEN.—Produce edema of lungs and, if in sufficient concen- tration, may cause death. 6. CARBON MONOXIDE.—If in sufficient concentration, will produce anoxemia, causing loss of consciousness and death. 40 RESTRICTED RESTRICTED ATSC MANUAL No. 25-3 Section XXVIII Removing fumes by local exhaust ventilation. Use of goggles in oxyacetylene welding. Ventilation turned off. Note the heavy concentration of fumes. The design of the local exhaust ventilating system for this welding operation provides for flexibility of location of the exhaust inlet. RESTRICTED 41