Notes of lectures on Physics Given at the Edinburgh Institution School Queen this Edinburgh By Robert Ferguson PHD. Headmaster in the session 1860 to 1861 By Thomas Lauder Bruton Capillary attraction Instances of it in common life Water rising in sugar or salt blotting Paper & c. When liquids wet a solid the liquid becomes cupped up at the edges of this vessel, when the liquid does not wet the solid it becomes cupped down For example in A a vessel filled with water which wets the edges of the vessel the liquid is cupped up & in B a vessel filled with mercury which does not wet the sides the liquid is cupped down. The narrower the vessel the more perceptible is this cupping until in tubes which have a hair-like bore the liquid rises or sinks very 3 considerably. Exp. Two plates of glass close at one end & Separated at the other when put into water. The water rose very considerably at the end at which they touched & scarcely rose at all at the other end A row of tubes of different sizes fixed in a Fram AA & having one eve put into a vessel of water, the water in the tubes rose to differ- ent heights according to this size of the tube. When ropes are wetted they shortern beacause the capillary tubes are filled with water and the ropes swell in thickness and shorten in length When a doctor wishes to bandages very tightly he puts on the bandage dry & wets it afterwards Some effects of liquids not wetting Solids. The little insects that run on water Have their limbs greasy or dusty so That the water does not wet them & the repulsion of the water is suf- ficient to counterbalance their weight so that they do not sink A needle can float on water for the same reason. An exp. Showing capillary attracted. A piece of cane is put into some turpente in a small phial & one end set fire to as long as the cane is in the turpenter the flame burned up but when the cane is taken out the cane burns without flame. 5 A liquid when confirmed in a close vessel transmits pressure equally in all directions V a close vessel entirely filled with water with 2 collars 130 C of exactly the same size which are fitted with 2 pistons moving easily, if a pressure of one lb be exerted on one piston a pressure of one lb is exerted on the other R a close vessel having 2 collars A & B fitted with pistons is being 20 times larger than A if a pressure of 1 lb be exerted on A, 20lbs pressure will be exerted on B. When water is confined in a close vessel and one square inch be expos- ed to a certain pressure say 1 lb every s-q. inch in the vessel is ex- posed to the same. 6 Bramah's press is a practical illustration of this principle AB is a lever handle with the hinge at B. P is a forcing pump. Lifting AB the value at Q opens & that at R shuts. Pressing down AB,Q shuts, R opens & the water is driven into the close Chamber C pressing up the piston S with a force greater than that exerted on AB in proportion to the size of the piston S as compare with that of S’. To prevent the water getting out at the side of the piston S there is a leather collar fixed to C.C. the sides of the chamber. When the water is pumped in it press not only upwards but presses the call 7 also sideways against the piston so that the more the water presses the closer the collar presses on the piston. The Brittania bridge over the menai straits consisting of tubes of iron honey combed to give greater strength & lightness, as shown at A, & weigh- ing 1.00 tons was raised by 2 of Bramahs presses placed on 2 of the pillars which were to sup- port the bridge with 2 men at each press. On one occasion the chains broke & the bridge fell 2 in. it was calculated that if it had fallen 1 ft the shock would have broken the bridge to pieces. The casting of the press for the Brittania bridge was the largest 8 casting ever made being 10 ft thick. After standing 72 hours it was still red hot & it was only after 10 days that the workmen could handle it. Bramahs press is also used by bookbinders. Water rises to its own level whatever the nature of the tubes in which it is placed A a vessel consisting of three tubes of different shapes, but connected together at the foot if water (which may be tinged with some colour that it may be better seen) is poured into one it will stand at the same height in all. When two columns of liquid Balance each other one of which 9 is heavier than the other the heights of the columns are inversely as their weights thus if a column of water bal- ances a column of mercury it requires to be 14 times higher mercury being 14 times heavier than water CD a column of water – AB the difference between the levels of B & D of the mercury X 14. The pressure of a column of liquid is in proportion to the height and not to the thickness of the column mountains may be burst by the pressure of water If in the mountain M there be a wide hor- izontal crack R & another 10 narrow crack C extend from R in a perpendicular direction & if R & C be filled with water by the rain if C be a sufficient height the mountain will burst If C be 1 sq in & the weight of the water in it be 60 lbs a weight of 60 lbs will be exerted on every sq in in R. Apparatus for showing that the hug pressure of a column of water is in proportion to its height 1 no to its bulk T,T,T,” tubes of different sizes & shapes but of the same perpendicular height & screwing on to a stand S by means of a collar C fixed to each tube. G a graduated tube with mer 11 in it. If T,T,T” be filled with water the mercury will stand at the same height in G though T contains 3 times as much water as T’, & T” is longer than either T or T’, being bent, though its perpendic- ular height is the same The hydrostatic bellows consist of two boards B.B. connected water- tight by a piece of strong leather L, into the upper of these two boards a long tube T with a funnel sop is fixed. When water is poured into T so as to fill the bellows and rise in the tube T the upper board rises with force suffic- ient to lift a considerable weight At Dr.R.M.Fer- gusons lectures Charles Cunningham son of Principal Cunningham was the weight lifted 12 To illustrate the pressure of water in all directions C is a cylinder of glass provided with a brass collar B at the lower end into which a piece of brass F exactly fits. S is a piece of silk thread by which F may either kept fitting into B or allowed at pleasure to drop which in a it does by its own weight. On pulling F into B & then putting C into a jar of water J, F & till rem in B although S is let go, being kept in its place by the upward press of the water in J. Fig 2nd B is a cylinder of glass open At both ends A a loose piece of glass. If A is laid on the end of B & both put 13 Fig.2 into a vessel of water C, A will not fall off from B being kept on by the pressure of the water in C. A is a glass cylinder open at the top & closed at the bottom & having a small tube C fixed in the side & pressing against a piece of brass B, when water is poured into A the side pressure of the water force A away from B. 14 In a canal C, a side pressure is exerted by the water in the direction of the arrows & if the banks are not sufficiently strong they will give way. Archimedes’ Principle When a body is immersed in a fluid it loses as much of it weight as equals the weight of the quan tity of fluid it displaces. B is a balance C is a follow cylinder of brass into which a solid piece of brass D exactly fits, into the par at the other end of the balance a weight is put which counter poises C & D. When D is put into a vessel of water E the pan P & in 15 the weight of D being lessened. P is now lightened till the balance is equal & the difference of weight noted. D is now taken away & C is weighted; it is then filled with water & the difference, which is the weight of water equal in bulk to D, again noted. If the experiment has been rightly performed the differences will be equal. The specific gravity of a body is the weight of any portion of it compared with the weight of the very same portion of water at the temperature of 60°Faren- heit, 60° being the ordinary sum mer heat Example. Weight of a piece of brass in air 79 grams -in water 69 - 79-69=10 diff. between water in air & in water G = specific gravity = 49/10 = 7.9 16 Cartesian divers are hollow fegines of glass. They are balanced just to float in a tall glass jar filled to within ¼ inch of the top with clear water and covered at the top with a piece of sheet india rubber. If the rubber be pressed with the finger the air is compressed, which acting on the water forces more water into the figures which are thus rendered specifically heavier and sink. On removing the finger the air again expands & the figures rise. When a body floats on a liquid it displaces as much of that liquid as will have its own 17 weight hence bodies that sink displace their own bulk of water bodies that float their own weight By the Archimedean principle I can ascertain the wt of an am- ount of water equal in bulk to that of solid by weighing that solid in air & then in water the diff. off the wts being the wt of the bulk of water required. For taking the S.G. of a solid lighter than water you must attach a sinker to it. Example. A piece of cork with a silver sinker weight of silver in air = 28.3 grams “ - “ “ “ water = 25.52 “ wt of water = in bulk to silver 2.78 wt of cork in air = 3. grams -----“ “+ silver = 31.3 “ “ “ “ in water = 9.4 “ 31.3-9.4=21.9 wt of volume of water equal in bulk to silver + cork 18 But the wt of water equal in bulk to silver = 2.78 21.9-2.78=19.12=(wt of water=cork in bulk) But S.G of cork=wt in air wt of equal volume of water which is = 3./19.12=.156 S.G of cork S.G of different bodies Ag 10.18 53°Fahr Pt 22.1 Au in coins 19.36 Ng 13.6 Pb 11.44 Cu hammered 9 Brass 8.4 Steel 7.8 Fe malleable 7.79 Fe cast 7.25 In hammered 7.86 --un------- 7.21 diamond 3.5 marble 2.84 Quartz 2.7 19 Bottle glass 2.64 window “ 2.45 flint “ 3.44 Ice .93 Boxwood 1.33 Ebony 1.23 Heart of oak 1.17 Lime .6 Cork .24 Sulph.acid 1.85 Milk 1.03 Sea water 1.03 Linseed oil .94 Olive oil .92 Oil of Turpentine .87 Alcohol .79 Sulphuric ether .73 That cold water is heavier than hot is shown by a hollow metal spere very delicately adjusted so that it will float in cold water but sink when the water is warmed. 20 The S.G. of liquids is best ascertained by means of the S.G. bottle The S.G bottle contains at a temperature of 60°Fahr. 1000 grains of distilled water. In order to prevent air bubbles remaining in the bottle the stopper has a small hole through it which is also filled with water, & then the outside of the bottle & stopper is carefully wiped Example. To ascertain the S.G. of alcohol. Fill the S.G. bottle with alcohol at 60° & weigh it wt = 54.5 grams But a gram = 15.4 grains 54.5 grams = 839.3 grains But the wt of the same quantity of water 21 equals 1000 grains. The S.G. of al- cohol = 839.3/1000=.8389 S.G of alcohol The S.G of the strongest alcohol = .79 It is of importance in the excise to ascertain readily the S.G of a mixture of alcohol & water To ascertain this by the S.G bottle would occupy too much time they consequ- ently use for this purpose Araom eters.These are loaded with mercury which sink to a certain extent in the liquids in which they are put, if the liquids be rare these sink very considerably in them if they be dense they do not sink so fast. The Araometers are so graduated that by means of a table which accompanies them the S.G is at once given & the relative proportions of alcohol & water in the mixture spirit which contains an equal mixture of alcohol & water is called 22 proof spirit, mixtures con- taining a larger quantity of alcohol are said to be over proof A mixture of 20 over proof would require 20 galls. of water to the 100 to make it proof & a mixture of 20 under proof would require 20 galls. of pure spirit to 100 to make it proof. Araometer = Hydrometer The best graduation for araomet- ers is Gay Lussac’s 1 is for fluids heavier than water 2 for fluids lighter than water Examples of taking the S.G by the araometer. No 1 in sulphuric acid stands at 23 54. 100/54 = 1.851 = S.G of sulph. Acid In alcohol no 2 stands at 119 100/119 = .84 = S.G of alcohol. Nichols arometer for ascertaining the wt of gems&c. This araometer has a standard point S to which the araometer is sunk & a perforated bag B in which the gems&c. are put Example. A piece of glass. To sink the araometer requires 5.415 grams. Weight required when the glass is laid on the top 3.54. At this time the glass fell into the water & we proceeded with suppositious weights. Supposed wt required with the 24 glass in B 4. 5.415-3.54 = 1.875 wt of glass in air 5.415-4 = 1.415 “ “ “ water .460 diff of wts 1.875/.460 = 4. S.G of glass To find the wt of bodies lighter than water reverse the cup. Fig 1 Section of ship. m. the metacentric or centre of gravity of the displaced fluid. G the centre of gravity of the ship. G must be below M Fig 2 If the ship be thrown sideways as 25 in Fig 2 but M be above G the force of the water pressing upward & of gravity pressing downward right the ship Fig 3 If however as in Fig 3 G should be above m, the waters pressing up ward & gravity pressing down ward overturn the ship. In all ships the centre of gravity should lie very low & the lower it lies the safer the vessel is. In order to prevent the vessel being So much laid over by a gust of wind as to bring G above m the Reel is put on the vessel which offers a great resistance to being dragged quickly through the water sidewise 26 Pneumatics There are three states of aggregate condition in bodies, solid, liquid & aeriform In solid bodies particles are kept together by the force of cohesion In gaseous or aeriform bodies instead of cohesion there is repulsion and in liquid bodies there is a balance between repulsion & cohesion Example of the repulsion of the particles of aeriform bodies towards each other or tendency to fill as large a space as possiple. If a bladder half full of air & tied at the mouth be put under the receiver of an air pump & the air exhaus- ted,the air in the bladder will expand & distend the bladder 27 Air possesses weight F is a strong glass bottle furnished with A stopcock. The air is exhausted the stopcock shut & the bottle weigh ed,the stopcock is then opened & the bottle again weighed, the diff. of the 2 wts being the wt of the air contained in the bottle Example of the repulsion of the particles of air. F is a brass framework, W a lead weight sliding up & down in F, B is a small india rubber bag laid under w, when F is put into a receiver & the air ex hausted the air in B expands 28 with force sufficient to raise w Heron's fountain consists of an upper vessel B an under vessel C, the tube D passes from a basin A into C & P, passes from the top of C nearly to the top of B & the tube F ending in the jet J passes nearly to the top of B. A little water is poured into B thro’ S & then water is poured into A, which passing thro’ D into C compresses the air there, which again acting on that on B compresses it likewise & drives the water out at J. Example of atmopheric pressure. 29 A tin canister with a stopcock & a Ittle water in the bottom is put over a spirit or gas lamp & the water boiled till steam is seen issuing briskly from the stopcock which is then shut & cold water poured over the canister. The steam being condensed leaves a vacuum & there being no resistance to the pressure of the external atmos- phere the canister is crushed The wt of air on a man is 14 tons. We feel lighter in air than we would in a vacuum as it deprives us of as much of our wt as the wt of the air we displace. 30 Pipettes or dropping tubes. As long as the finger is kept on the aperture at A nothing flows while if the finger is taken off there is a greater or less flow according to the time the finger is kept off. A magic pitcher is double & has one hole which may be stopped with the finger at A & another at B. As long as the finger covers A there is no flow but whenever it is taken off the water flows out at B. The magic filler is on the same principles 31 A small glass vessel R open at both ends has a piece of bladder B tied over one end & the air exhausted the pressure of the atmosphere bursts the bladder Apparatus for keeping a liquid at the same level. A is a glass vessel having a stopcock at S & an aperture C into which the neck of a florence flask B filled with the liquid is pull whenever the liquid in A falls beneath the mouth of B, that in B runs into A till the liquid in A again stands above the mouth of B, & so on till B is empty 32 A lamp on the same principle The shoulder blades & knee pains are kept in their place by the pressure of the air. A boys sucker is an instance of the pressure of the air. The shoulder blades are kept in the same way as a stone to a sucker All the joints are kept in position by the pressure of the air A german anatomist cut away all the flesh & ligaments about a hip joint but still the leg swung in its place, he then bored a hole at it 33 when the leg at once fellout. He then put it in again & put his finger on it. While his finger was on A the leg staid in but as soon as he took away his finger the leg fell out. H is the handle of a pump P the piston In pulling up the Handle H, P goes down the valve at R shuts & that at S opens the air passing out at S. When H is pull ed down P goes up the valve S shuts & R opens water rushing through it to Fill up the vacuum caused by pull- ing up P. When P goes down a second time R closes & S opens water rushing through it. When P again comes up it draws up tho water along with it The cistern C keeps up a constant stream 34 The pump acts theoretically at 34ft but practically at about 20ft The ancients accounted for the working of the pump by saying that nature had a horror of oral horred a vacuum. Horror vacui. A force pump differs from a com- mon Pump in having no value In the piston, but one at R in a bose attached to the side of the pump The force pump draws up the water in the same manner as a common pump but at the return stroke instead of the water passing through the piston it is driven through R & out at A with a force proportionate to the 35 downward pressure of the piston Water is forced out only at the downward stroke of the piston The air cushion or chamber is a strong vessel having a tube furnished with a stopcock passing from the top almost to the bottom of it The stopcock is shut & the chamber fast connected with a force pump Water is then pumped in till the air in the chamber is considerably compressed. The stopcock is then opened & the water rushes out in a constant stream the air keeping up a pressure on the water in the chamber between the strokes of the pump 36 A fire engine consists of two force pumps & an air chamber. A is connected to a water pipe. Torricelli a pupil of Galileo’s first discovered that the action of the pump was due to the pressure of the atmosphere The Duke of Tuscany was get- ting a pump to draw water from a well 50 ft deep, the pump was of copper and as good as they could make it. However the water would not rise above 34 ft. Galileo on being asked the cause said that nature abhorred a vacuum as far as 34 ft but no further. He had however a sus- 37 picion that it was due to the pressure of the air Torricelli reasoned that if it was due to the pressure of the air, as mercury is 13.6 times heavier than water, the air which balanced 34 ft of water ought to balance 34 ft/13.6 = 30 in. of mercury. He then look A tube about 3 ft long & closed at one end, this tube he filled with mercury & then plunged the open end into a cistern filled with mercury so that no air could get into the tube, the mercury in the tube sinking to 30 in. above the level of the mercury in the cistern at once confirmed his hypothesis The wt of column of mercury whose Height is 30 in & base 1 sq in is 14½ lbs & as the air balances a column of mer- cury of that height. The wt of a col umn of air whose base is 1 sq in is equal to 14½ lbs. 38 The air has been compared to wool of which if you take one flake in density is very slight, but if you take flake after flake & pile them upon each other to a considerable height, the bottom flakes become much denser the density of the flakes diminishing as you get nearer the top of the pile. Although the atmosphere extends to about 80 mils above the sur- face of the earth yet the air near the earth is so much denser than the rest that you pass ½ of the atmosphere at a height of 3 miles Pascal reasoned if on the surface of the earth the air can support so much mercury it will not support so much on the top of a high mountain there being less air above it. The mercury falls in proportion to the height 39 of the mountain. A is a tube filled with mercury & inverted into a cistern with merc- ury B which is then sealed up leaving only a small opening C Fig 1 is the apparatus in its nat ural state. When the air in B is densified by blowing in the merc ury in A rises to the top of the tube as in Fig 2. When as in Fig 3 the air is rarefied by sucking the mercury falls in A Puy de Dome was the 1st moun- tain Whose height was taken by The barometer. 40 The common cistern barometer has this disadvantage that as the mercury falls in the tube it rises in the cistern the mercury which was in the tube flowing into the cistern & vice versa The syphon barometer has not this disadvantage since the height of the mercury is always taken from the level of the mercury in the smaller limb. 41 In every case you take the height of the mercury in the tube above the mercury in the cistern. In the best cistern barometers such as mountain barometers the cistern has a leather bottom which may be raised or lowered by means of a screw till the mercury stand at a standard point which is mark- ed by a needle A. The barometer goes between 28 & 31 in. At the mouth of the La Plate river the barometers read the different way When the east wind blows the barom 42 stands high because the wind is cold. When the west wind flows the barr stands low because the wind is hot You cannot tell the weather from one observation of the baromr but from its tendency. A sudden fall indi- cates a storm. To take the ht of a mountain by the barometer. Example. With suppositious heights of the baromr At the foot of mountain 29.87 in 62°Fahr. -------top--------------29.1 in 52°----- To reduce these heights to the same pt of the thermometer subtract 32° the freezing pt. 62°-32°=30° 52°-32°=20° Mercury expands 1/10000 th part for every degree of Fahrenheit. 30/10000 of 29.87=.089 20/10000 of 29.1=.058 43 29.87-.089=29.078 corrected wts 29.1-.058=29.042 ------------ Subtract the logs of the 2 corrected wts log 29.781=1.4739247 29.042=1.4630265/.0108982 fathoms 1000/108.982 approximate wt Add the 2 temperatures & take the half. 62+52=114/2=57 mean temperature Correct ht=460+57/492X108.982=56343.694/492=114.51 fathoms 114.51 fathoms=687.06 ft The aneroid bar. consists of an iron box with a corrugated top & partially exhausted of air when the pressure of the air is greater the top of the box is forced down & when the pressure of the air is less the top rises up & by means of some mechanism these 44 risings & fallings of the top are communicated to an index hands which moves round over a palate m [???ed] with rain, fair’ & c. The compressed air fountain consists of a copper vessel A a basin B & a tube c which passes nearly to the bottom of A. There is a jet at the top of c which being screwed off a syringe is fiaed on & the air pumped in. The jet is then screwed on & the compressed air in A drives out the water with con- siderable force. Miscellaneous notes. Composition for lining the in- side of chauffers Patiently mix fresh Stourbridge clay with a little horse dung & add about 1/6 of a powder made by pulverizing old crucibles The composition must not be applied too moist & is to be al- lowed to dry spontaneously. The cracks must be filled up with fresh composition. When quite dry a gentle fire is made & gradually increased to the highest pitch by the bellows. The crucible is supported about 3 in. from the bottom. A piece of brick on a thin stratum of sand is a good support. Luting for crucibles Sifted Stourbridge clay will Mixed with a little damp horse dung to wt a small quan tity of strong solution of borax has been added. It should be applied with a knife. Self acting blow pipe 1 has some alcohol in it 2 is a cork to act as a safety valve. The heat evaporates the spirit wts issues at 3 & acts instead of wind. Tube retorts. H is 2 iron hemispheres lined with lead or 2 lead ones for making HFL. C. to make HCL. 46 Cement of glass & metal up to 212°F. To cement glass to metal a mixture of equal parts of red & white lead is better than white Lead alone. If the cemented pieces placed on a sand bath for a few days the mixture be- comes very hard. The glass should be roughened & a little tow wrap- ped round the part where it is to be applied. Apparatus for obtaining the electric Spark in damp rooms Rub a large porcelain tube 3 ft long & 1½ in thick with a piece of the best silk covered with am- algam. Only half of that portion Of the silk in contact with the tube has amalgam on it. To charge the jar water is 3 in high & 1 in in diameter hold the tube in front of the iron wire with water the jar is mounted & employ brisk friction with the silk, the amalgam is made by heating 2 parts Hg & 1 part of thin Ln foil to water 1 part Ln is added while stirring, it is to be melted & stirred several times before being applied to the silk. a is a Cu. Head made to slip tightly into the aperture of the glue pot b. A small tubulature c permits the passage of a thermometer or the addition of any substance during the progress of the distill ation the seams of the head are all brazed the picture of the haed with the pot is luted with almond & linseed meal If it be desired to distil with a glass tube to carry the products into the condenser I have the Cu. cover 48 attached to the pot It is to be luted in the same manner as the head. If it is wished to distil at a gentle heat such as 212°F & attach a some what smaller head to the water bath of the glue pot. Pipettes. 1 is an india 1. rubber ball. Compress the ball plunge 2 under the liquid you wish to draw up. Let 1 expand & the liquid rushes up the tube Should Cl be inhaled, inhale steam, a very little ammonia added to the HO increases its efficacy Safety tube Pastilles for cutting glass 2½ oz gum arabic & ½ oz gum traga- canth dissolved in 5½ oz of HO. Then ¼ oz storan & 1/4 oz gum benzoin are dissolved in 1½ oz spirit of urine the 2 mixtures are to be worked with 3½ oz powdered charcoal into a stiff paste oz ½ oz gum tragacanth in powder is dis solved in HO to an elastic mucilage allowing it to macerate for about- 1 hour. Then add ¼ oz benzoin dissolved in sufficient & spirit Rub the 2 fluids in a mortar with as much powdered charcoal as will form a tenacious paste The pastes formed by either pro cess are to be formed into sticks about the size of quills & slow- ly dried in the water bath The benzoin is not essential. A little linseed oil strengthens them. Holes may be bored in thick glass by a bradawl dipped in turpentine Pyrotechnical knot The champagne knot Bee hive shelf Gas lamp. Place a funnel shaped tube over a gas jet. The neck of a broken glass retort will do To prevent dissipation of heat from flasks. Take a tin cone about 7 in D at the base, 6 in. high & having a hole cite at the apex about 1 in. in D. thro wts the neck of the flask may pass. If a flask is in danger of boil- ing over blow on the part above the level of the fluid. To make a retort stand take a piece of wood about 12 in. long. 6 in. wide & 1 in. thick fix the rod about 1½ from one end. To heat a retort quickly, cover part of it with a cardboard cone with a notch in it to admit the neck. Table blow pipe. Valve to prevent The return of air. Take a piece of tube of about This D. with a smooth & level end, & a piece of black oiled silk of a width rather more than the external D. of the tube, or a piece of ribbon of the same width wts has been rubber with wax. Adjust this loosely over the end of the tube, fold the extrem ities down on opposite sides & tie them with a piece of thread the silk itself not being so tight but that air may be blown between the tube & silk. Fix this tube to a large bladder placed between boards, or to a bag of cloth air tight by canutchouc or of oiled silk. The tube by wts the air is blown in must have another valve of the same sort. Mixture for electrophorous Equal parts of common resins shell lac & venice turpentine are to be mixed together & heated in a metallic vessel, the mixture being kept fused at from 230° to 240° till nearly all evolution of vapour has ceased & the fluid is quiet. Allow it to cool till it thickens & then pour it out tranquilly Notes on the Calotype Process Gun Cotton 1 lb by weight Nitrate of Potass 1 “ by measure sulphuric Acid mix and stir well with glass rods, then get help to put in the best carded cotton wool in small lots and be careful to get the liquid thoroughly through the cotton or the cotton will burn away strong red coloured sulphuric fumes. When suffi ciently cotton has been put in to take up all the liquid let the whole lie for about 15 or 20 minutes (except an occasional stir) & then wash to get away all the acid from the cotton otherwise the collodion will be of no use, then dry & put aside for use. By the taste or the use of Lit mus paper it may be known if the cotton is free from acid When acid is left in the cotton the collodion becomes red in colour & will not wash easily and if the cotton is not thor oughly dry the collodion is of a blueish tint & does not Work well. Collodion Is made by dissolving six grains of Gun Cotton in one oz of the best rectified spirit of wine. Iodizing solution Iodide of Cadmium ℥ grains ’’ ’’ ’’ Ammonium ℥ ’’ ’’ ’’ Potassium ℥ ---- Bromide------------ 3 ---- Alcohol 1 oz oz Iodide of Cadmium 10 grs --- --- Potassium 8 --- Bromide of Cadimium 4 --- Alcohol oz 1 oz Iodide of Ammonium 10 grs ’’ -- Cadmium 10 --- Bromide -- 3 Alcohol __________ 1 oz The Iodizer is applied in the proportion of 2 drams to 6 drams of collodion for negatives & 1½ drams to 6½ drams of collodion for Positives Collodion must be iodized at least 24 hours before working. To take pictures the glasses must be scrupulously clean Pour on the collodion at one corner of the glass & run it Negative Photographic Formulas Young-Photographer Galashiels Iron Developer Sulphate of iron 18 grains Acetic acid 20 minims Alcohol 20 minims Water 1 ounce Redeveloper Equal quantities of these solutions Pyrogallic acid 5 grains Citric acid 2 grs Water 1 ounce Nitrate of silver 10 grs Water 1 ounce Ioning Bath Chloride of gold 1 gr Water 1 oz Bicarbonate of soda 3 grs Water 1 ounce One ounce of gold solution && 1 of soda solution to 6 ounces water Med. Hist. MS. B 71